HKB
Dr. Daubeny has remarked, that muriatic acid may have ceased to be disengaged, because the volcanic action has become languid in equatorial America, and sea-water may no longer obtain admission.
M. Gay Lussac, while he avows his opinion that the decomposition of water contributes largely to volcanic action, called attention, nevertheless, to the supposed fact, that hydrogen had not been detected in a separate form among the gaseous products of volcanoes; nor can it, he says, be present; for, in that case, it would be inflamed in the air by the red-hot stones thrown out during an eruption. Dr. Davy, in his account of Graham Island, says, "I watched when the lightning was most vivid, and the eruption of the greatest degree of violence, to see if there was any inflammation occasioned by this natural electric spark--any indication of the presence of inflammable gas; but in vain."[765]
May not the hydrogen, Gay Lussac inquires, be combined with chlorine, and produce muriatic acid? for this gas has been observed to be evolved from Vesuvius--and the chlorine may have been derived from sea salt; which was, in fact, extracted by simple washing from the Vesuvian lava of 1822, in the proportion of nine per cent.[766] But it was answered, that Sir H. Davy's experiments had shown, that hydrogen is not combustible when mixed with muriatic acid gas; so that if muriatic gas was evolved in large quantities, the hydrogen might be present without inflammation.[767] M. Abich, on the other hand, assures us, "that although it be true that vapor illuminated by incandescent lava has often been mistaken for flame," yet he clearly detected in the eruption of Vesuvius in 1834 the flame of hydrogen.[768]
M. Gay Lussac, in the memoir just alluded to, expressed doubt as to the presence of sulphurous acid; but the abundant disengagement of this gas during eruptions has been since ascertained: and thus all difficulty in regard to the general absence of hydrogen in an inflammable state is removed; for, as Dr. Daubeny suggests, the hydrogen of decomposed water may unite with sulphur to form sulphuretted hydrogen gas, and this gas will then be mingled with the sulphurous acid as it rises to the crater. It is shown by experiment, that these gases mutually decompose each other when mixed where steam is present; the hydrogen of the one immediately uniting with the oxygen of the other to form water, while the excess of sulphurous acid alone escapes into the atmosphere. Sulphur is at the same time precipitated.
This explanation is sufficient; but it may also be observed that the flame of hydrogen would rarely be visible during an eruption; as that gas, when inflamed in a pure state, burns with a very faint blue flame, which even in the night could hardly be perceptible by the side of red-hot and incandescent cinders. Its immediate, conversion into water when inflamed in the atmosphere, might also account for its not appearing in a separate form.
Dr. Daubeny is of opinion that water containing atmospheric air may descend from the surface of the earth to the volcanic foci, and that the same process of combustion by which water is decomposed may deprive such subterranean air of its oxygen. In this manner he explains the great quantities of nitrogen evolved from volcanic vents and thermal waters, and the fact that air disengaged from the earth in volcanic regions is either wholly or in part deprived of its oxygen.
Sir H. Davy, in his memoir on the "Phenomena of Volcanoes," remarks, that there was every reason to suppose in Vesuvius the existence of a descending current of air; and he imagined that subterranean cavities which threw out large volumes of steam during the eruption, might afterwards, in the quiet state of the volcano, become filled with atmospheric air.[769] The presence of ammoniacal salts in volcanic emanations, and of ammonia (which is in part composed of nitrogen) in lava, favors greatly the notion of air as well as water being deoxidated in the interior of the earth.[770]