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Experimental Researches in Electricity, Volume 1

Michael Faraday · 1831-1838 (series of articles); Preface dated March 1839; this volume reprinted 1849 primary

passage 78 of 401 · (78/401)

↪ you wandered here via “freezing mixture ice salt” — the connecting lines are tinted below

in brief
Faraday begins “On a new Law of Electric Conduction,” showing that ice is a non-conductor in frozen conditions, but conduction and electro-chemical decomposition resume when a thin film of ice melts.

between the platina and tin; and finally these metals were connected with the opposite extremities of the voltaic apparatus, a galvanometer being at the same time included in the circuit.

  1. In the first experiment, the platina pole was three inches and a half long, and seven eighths of an inch wide; it was wholly immersed in the water or ice, and as the vessel was four eighths of an inch in width, the average thickness of the intervening ice was only a quarter of an inch, whilst the surface of contact with it at both poles was nearly fourteen square inches. After the water was frozen, the vessel was still retained in the frigorific mixture, whilst contact between the tin and platina respectively was made with the extremities of a well-charged voltaic battery, consisting of twenty pairs of four-inch plates, each with double coppers. Not the slightest deflection of the galvanometer needle occurred.

  2. On taking the frozen arrangement out of the cold mixture, and applying warmth to the bottom of the tin case, so as to melt part of the ice, the connexion with the battery being in the mean time retained, the needle did not at first move; and it was only when the thawing process had extended so far as to liquefy part of the ice touching the platina pole, that conduction took place; but then it occurred effectually, and the galvanometer needle was permanently deflected nearly 70 deg..

  3. In another experiment, a platina spatula, five inches in length and seven eighths of an inch in width, had four inches fixed in the ice, and the latter was only three sixteenths of an inch thick between one metallic surface and the other; yet this arrangement insulated as perfectly as the former.

  4. Upon pouring a little water in at the top of this vessel on the ice, still the arrangement did not conduct; yet fluid water was evidently there. This result was the consequence of the cold metals having frozen the water where they touched it, and thus insulating the fluid part; and it well illustrates the non-conducting power of ice, by showing how thin a film could prevent the transmission of the battery current. Upon thawing parts of this thin film, at both metals, conduction occurred.

  5. Upon warming the tin case and removing the piece of ice, it was found that a cork having slipped, one of the edges of the platina had been all but in contact with the inner surface of the tin vessel; yet, notwithstanding the extreme thinness of the interfering ice in this place, no sensible portion of electricity had passed.

  6. These experiments were repeated many times with the same results. At last a battery of fifteen troughs, or one hundred and fifty pairs of four-inch plates, powerfully charged, was used; yet even here no sensible quantity of electricity passed the thin barrier of ice.

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topics: experiment, observation, and evidence · matter, motion, and cause

Experimental Researches in Electricity, Volume 1 · Michael Faraday · 1831–1838